In 68 premier League games against Manchester United the reds have had 9 players sent off.
| Min | Player | Date | Score | Opposition | Competition |
|---|---|---|---|---|---|
| 38 | Jonjo Shelvey | 20.09.2012 | 1 - 2 | Manchester United | Premier League |
| 46 | Steven Gerrard | 22.03.2015 | 1 - 2 | Manchester United | Premier League |
| 40 | Michael Owen | 10.04.1998 | 1 - 1 | Manchester United | Premier League |
| 68 | Danny Murphy | 31.03.2001 | 2 - 0 | Manchester United | Premier League |
| 3 | Sami Hyypia | 05.04.2003 | 0 - 4 | Manchester United | Premier League |
| 44 | Javier Mascherano | 23.03.2008 | 0 - 3 | Manchester United | Premier League |
| 90 | Javier Mascherano | 25.10.2009 | 2 - 0 | Manchester United | Premier League |
| 38 | Jonjo Shelvey | 20.09.2012 | 1 - 2 | Manchester United | Premier League |
| 46 | Steven Gerrard | 22.03.2015 | 1 - 2 | Manchester United | Premier League |
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