| Match # | Date | Round | Opponent | H/A | Result | Score | Att |
|---|---|---|---|---|---|---|---|
| 238 | 22/02/2005 | KO 1L | B Leverkusen | H | W | 3-1 | 40,942 |
| 258 | 21/02/2006 | KO 1L | Benfica | A | L | 0-1 | 63,702 |
| 268 | 21/02/2007 | KO 1L | Barcelona | A | W | 2-1 | 93,641 |
| 283 | 19/02/2008 | KO 1L | Inter Milan | H | W | 2-0 | 41,999 |
| 297 | 25/02/2009 | KO 1L | Real Madrid | A | W | 1-0 | 85,000 |
| 372 | 14/02/2018 | KO 1L | Porto | A | W | 5-0 | 47,718 |
| 385 | 19/02/2019 | KO 1L | Bayern Munich | H | D | 0-0 | 52,250 |
| 399 | 18/02/2020 | KO 1L | Atletico Madrid | A | L | 0-1 | 67,443 |
| 407 | 16/02/2021 | KO 1L | RB Leipzig | A | W | 2-0 | n/a |
| 417 | 16/02/2022 | KO 1L | Inter Milan | A | W | 2-0 | 37,918 |
| 430 | 21/02/2023 | KO 1L | Real Madrid | H | L | 2-5 | 52,337 |
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