| Games Won | Games Drawn | Games Lost |
| 5 | 1 | 2 |
| Date | Match | Result | Score | Competition |
| 12 Sep 2006 | PSV Eindhoven v Liverpool | D | 0-0 | UEFA Champions League |
| 22 Nov 2006 | Liverpool v PSV Eindhoven | W | 2-0 | UEFA Champions League |
| 03 Apr 2007 | PSV Eindhoven v Liverpool | W | 0-3 | UEFA Champions League |
| 11 Apr 2007 | Liverpool v PSV Eindhoven | W | 1-0 | UEFA Champions League |
| 01 Oct 2008 | Liverpool v PSV Eindhoven | W | 3-1 | UEFA Champions League |
| 09 Dec 2008 | PSV Eindhoven v Liverpool | W | 1-3 | UEFA Champions League |
| 29 Jan 2025 | PSV Eindhoven v Liverpool | L | 3:2 | UEFA Champions League |
| 26 Nov 2025 | Liverpool PSV Eindhoven | L | 1:4 | UEFA Champions League |
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